A VOR was off by 5 degrees. List of problematic VORs?

Many of them are correct, and the avionics follow them correctly, at least for the G1000, G3000, G5000, and the weird narrow vertical Garmins in the SW121.

A few high declination examples, LittleNavMap vs WxBrief:

BOS:


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LFV:


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BTV:
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No. They don’t re-align the VORs over time. That would require changes to the physical equipment. The IFR charts specify the VOR radials based on the current orientation of the VOR at the ends of the lines, NOT a magnetic course. The VOR 0 degree radial orientation is the same as it was whenever it was last physically adjusted - 1965 for the case of EHK.

Once the physical VOR installation is in place, any additional magnetic variation over time is irrelevant.