Best options for screenshots?

You could use AutoHotKey which has macros to bind Joystick button presses and you can then simply trigger a keyboard keypress or execute a command or something like that:

A simple macro like

Joy3::Send #!{PrintScreen}

should do the trick (Win+Alt+PrtSc, default keybind for screenshots with the Gamebar). You just need to find out which button AutoHotKey has to react on.
Here’s a list of the Joystick identifiers that you can bind, there is also a testscript to identify a button when pressed:

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