CTDs with V-SYNC OFF and G-SYNC ON with no FPS Limits

Sounds exactly like an overheating issue.
Please check your gpu temp in the menu e.g. with task manager. I had the same problem. 3d mark and all other stress tests/ AAA games were fine but with MSFS your GPU gets hotter than normal. Anything near or above 90C would indicate that this is probably the issue.

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