Why Is Performance Better In My 10900K System Compared To My 13900K System?

Classic symptoms indicating your overclocked 4090 is too powerful for your cpu (or any cpu) at 4k. Things that may help -

Increasing resolution/ renderscale (if using DLSS then use DLAA with it)
Maximising gpu intensive settings
Decreasing cpu intensive settings (T-LOD, traffic)
Multimonitor
Hi end VR