Help with MSFS2020 EXE.XML File

Should read: F:\Downloads MSFS2020\FSUIPC\Version 7 Beta\FSUIPC7\FSUIPC7.exe

Numeric seven before the .exe

And then I think you need to wrap each property in tags as XML is pretty strict, see this thread: Start (multiple) programs on MSFS startup with this exe.xml 'tip'